Nickel‐Catalyzed Amination of Aryl Nitriles for Accessing Diarylamines through C−CN Bond Activation. Issue 20 (26th August 2021)

• Record Type: Journal Article
• Authors: Wu, Ke; Rong, Qiang; Sun, Nan; Hu, Baoxiang; Shen, Zhenlu; Jin, Liqun; Hu, Xinquan
• Is Part Of: Advanced synthesis & catalysis. Volume 363:Issue 20(2021)
• Page Start: 4708
• Page End: 4713
• Publication Date: 2021-08-26
• Subjects: Amination -- C−CN bond activation -- Nickel -- Diarylamines -- Aryl nitriles; Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.202100641
• Languages: English
• ISSNs: 1615-4150

Abstract

Abstract: A nickel‐catalyzed amination to access diarylamines has been developed through C−CN bond activation of aryl nitriles with anilines. In this developed catalytic protocol, various aromatic and heteroaromatic nitriles could be utilized as the electrophiles to couple with substituted anilines. A diversity of diarylamines were obtained in 15–95% yields. Abstract :