Galactose Grafted Two‐Dimensional Nanosheets as a Scaffold for the In Situ Synthesis of Silver Nanoparticles: A Potential Catalyst for the Reduction of Nitroaromatics. Issue 56 (3rd September 2021)

• Record Type: Journal Article
• Authors: Harikrishnan, Kaloor S.; Krishnan, Nithiyanandan; Kumar, Nilima Manoj; Krishna, Anusree; Raj, Gowtham; Perumal, Devanathan; Kalathil, Jemshiya; Krishna, Jithu; Varghese, Reji
• Is Part Of: Chemistry. Volume 27:Issue 56(2021)
• Page Start: 14100
• Page End: 14107
• Publication Date: 2021-09-03
• Subjects: amphiphiles -- catalysis -- supramolecular chemistry -- Tollens' reaction -- 2D nanosheet; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.202102421
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract: Two major hurdles in NP‐based catalysis are the aggregation of the NPs and their recycling. Immobilization of NPs onto a 2D support is the most promising strategy to overcome these difficulties. Herein, amphiphilicity‐driven self‐assembly of galactose‐hexaphenylbenzene‐based amphiphiles into galactose‐decorated 2D nanosheet is reported. The extremely dense decoration of reducing sugar on the surface of the sheets is used for the in situ synthesis and immobilization of ultrafine catalytically active AgNPs by using Tollens' reaction. The potential of the system as a catalyst for the reduction of various nitroaromatics is demonstrated. Enhanced catalytic activity is observed for the immobilized AgNPs when compared to the corresponding discrete AgNPs. Recovery of the catalytic system from the reaction mixture by ultrafiltration and its subsequent recycling for several cycles without dropping its activity is shown. This is the first report demonstrating the in situ synthesis and immobilization of ultrafine AgNPs onto a 2D nanosheet that exhibits excellent catalytic performance for the reduction of nitroaromatics. Abstract : Amphiphilicity‐driven self‐assembly of galactose‐hexaphenylbenzene based amphiphiles into galactose‐decorated 2D nanosheet is reported. The extremely dense decoration of reducing sugar on the surface of the sheets is used for the in situ synthesis and immobilization of ultrafine catalytically active AgNPs by using Tollens' reaction. The potential of the system as a recyclable catalyst for the reduction of various nitroaromatics is demonstrated. Enhanced catalytic activity is observed for the immobilized AgNPs when compared to the corresponding discrete AgNPs.