ChemInform Abstract: α‐MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents: Redox‐Neutral Rhodium(III)‐Catalyzed C—H Activation for the Synthesis of N‐Heterocycles. Issue 32 (24th July 2014)

• Record Type: Journal Article
• Authors: Yu, Da‐Gang; de Azambuja, Francisco; Glorius, Frank
• Is Part Of: ChemInform. Volume 45:Issue 32(2014)
• Page Start: no
• Page End: no
• Publication Date: 2014-07-24
• Subjects: isoquinoline derivatives -- fused pyridine derivatives -- fused pyrrole derivatives -- thiazine derivatives -- ring closure reactions -- catalysis, phase‐transfer catalysis; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201432174
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: For the first time, α‐pseudohalo and α‐halo ketones are utilized as oxidized alkyne equivalents in Rh(III)‐catalyzed redox‐neutral annulations to efficiently generate diverse N‐heterocycles.