Synthesis of high performance polyacrylonitrile by RASA SET–LRP in the presence of Mg powder. Issue 16 (27th May 2013)

• Record Type: Journal Article
• Authors: Chen, Hou; Lv, Gaojian; Liang, Ying; Sun, Jinming
• Is Part Of: Journal of polymer science. Volume 51:Issue 16(2013:Aug.)
• Page Start: 3328
• Page End: 3332
• Publication Date: 2013-05-27
• Subjects: kinetics (polym.) -- living radical polymerization (LRP) -- single electron transfer‐living radical polymerization (SET‐LRP); 547
• DOI: 10.1002/pola.26750
• Languages: English
• ISSNs: 0887-624X

Abstract

Abstract : High performance polyacrylonitrile (PAN) was prepared with Mg powder as both reducing agent (RA) and supplemental activator (SA) by single electron transfer‐living radical polymerization (RASA SET‐LRP). First‐order kinetics of polymerization with respect to monomer concentration, linear increase of molecular weight, and narrow polydispersity with monomer conversion, and the obtained high isotacticity PAN indicate that RASA SET‐LRP in the presence of Mg powder could simultaneously control molecular weight and tacticity of PAN. compared with that obtained with ascorbic acid (VC) as RA, an obvious increase in isotacticity of PAN was observed. the block copolymer pan‐ b ‐pAN with molecular weight at 112, 460, polydispersity at 1.33, and isotacticity at 0.314 was successfully prepared. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 3328–3332 Abstract : High‐performance PAN was prepared with Mg powder as both reducing agent and supplemental activator by RASA SET–LRP. First‐order kinetics of polymerization with respect to monomer concentration, linear increase of molecular weight and narrow polydispersity with monomer conversion, and the obtained high isotacticity PAN indicate that RASA SET–LRP in the presence of Mg powder could simultaneously control molecular weight and tacticity of PAN. Compared with that obtained with ascorbic acid (VC) as reducing agent, the increase in isotacticity of PAN was observed. The block copolymer PAN‐ b ‐PAN with molecular weight at 112460, polydispersity at 1.33, and isotacticity at 0.314 was successfully prepared.