ChemInform Abstract: Copper(I)‐Catalyzed One‐Pot Synthesis of Highly Functionalized Pyrrolidines from Sulfonyl Azides, Alkynes, and Dimethyl 2‐(Phenylamino)maleate. Issue 22 (15th May 2015)

• Record Type: Journal Article
• Authors: Ramanathan, Devenderan; Pitchumani, Kasi
• Is Part Of: ChemInform. Volume 46:Issue 22(2015)
• Page Start: no
• Page End: no
• Publication Date: 2015-05-15
• Subjects: pyrrole derivatives -- ring closure reactions, annulation reactions -- cascade reactions, domino reactions, tandem reactions -- multicomponent reactions; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201522151
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: This cascade reaction consists of an azide—alkyne [3 + 2] cycloaddition/ring rearrangement, ketenimine formation, an intermolecular nucleophilic addition sequence and subsequent intramolecular cyclization followed by [1, 3]‐H shift.