Determination and Monitoring of Quality Parameters: A Detailed Study of Optical Elements of a Lens-Based Raman Spectrometer. Issue 2 (February 2022)

• Record Type: Journal Article
• Authors: Mukherjee, Ashutosh; Lorenz, Anita; Brecht, Marc
• Is Part Of: Applied spectroscopy. Volume 76:Issue 2(2022)
• Page Start: 199
• Page End: 206
• Publication Date: 2022-02
• Subjects: Raman spectroscopy -- principle of Raman spectrometer -- spectral resolution -- full width half-maximum -- FWHM; Spectrum analysis -- Periodicals; 543.505
• DOI: 10.1177/00037028211055148
• Languages: English
• ISSNs: 0003-7028

Abstract

A lens-based Raman spectrometer is characterized by studying the optical elements in the optical path and we study the measure of aberration–diffraction effects. This is achieved by measuring the spectral resolution (SR) thus encompassing almost all optical elements of a spectrometer that are mostly responsible for such effects. An equation for SR is used to determine the quality factor Q which measures aberration/diffraction effects occurring in a spectrometer. We show how the quality factor changes with different spectrometer parameters such as grating groove density, the wavelength of excitation, pinhole width, charge-coupled device (CCD) pixel density, etc. This work provides an insight into the quality of a spectrometer and helps to monitor the performance of the spectrometer over a certain period. Commercially available spectrometers or home-built spectrometers are prone to misalignment in optical elements and can benefit from this work that allows maintaining the overall quality of the setup. Performing such experiments over a period helps to minimize the aberration/diffraction effects occurring as a result of time and maintaining the quality of measurements. Graphical Abstract