Diaryl‐λ3‐iodane Woven Supramolecular Architecture of Polyoxometalate. Issue 23 (22nd June 2020)

• Record Type: Journal Article
• Authors: Xiong, Zhelun; Wang, Fang; Ke, Degang; Wang, Yu; Huang, Bo; Xiao, Zicheng; Wu, Pingfan
• Is Part Of: ChemistrySelect. Volume 5:Issue 23(2020)
• Page Start: 7056
• Page End: 7059
• Publication Date: 2020-06-22
• Subjects: Polyoxometalates -- Diaryl-λ3-iodane -- Halogen bond -- Self-assembly; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.202001599
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: For the first time, diaryl‐λ 3 ‐iodane was employed as the cation of polyoxometalate (POM). The derivative exhibits a fascinating supramolecular architecture, which originates from halogen bonds between the cations and POM anion clusters. It is also the first proof of woven supramolecular architecture constructed by pure halogen bonds using POMs as multi‐dentate electron donors, providing a new vision for the design of POM‐based supramolecular architectures. Abstract : It is the first example that polyoxometalate‐based supramolecular architecture originating from halogen bonds was induced by the cations of diaryl‐λ 3 ‐iodane. It is also the first proof of woven supramolecular architecture constructed by pure halogen bonds using POMs as multi‐dentate electron donors, providing a new vision for the design of POM‐based supramolecular architectures.