Synthesis of hierarchical porous Prussian blue analogues in partially miscible ionic liquid/ethanol solution near the phase boundary. (13th January 2021)

• Record Type: Journal Article
• Authors: Song, Zongren; Ma, Xiaoxue; Kang, Xinchen; Wu, Yang; He, Zhenhong; Fang, Dawei
• Is Part Of: New journal of chemistry. Volume 45:Number 4(2021)
• Page Start: 1790
• Page End: 1794
• Publication Date: 2021-01-13
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/d0nj05619g
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : Hierarchical porous PBAs with excellent catalytic performance were controllably synthesized in a partially miscible IL/ethanol system. Abstract : A new strategy to synthesize hierarchical porous Prussian blue analogues uses nanodomains as the template in a partially miscible ionic liquid/ethanol system, especially near the phase boundary, is developed and the pore size is tuned by controlling the composition of solution in the single phase region. The as-synthesized hierarchical porous catalysts exhibit excellent catalytic performance in the epoxidation of styrene.