A novel photocatalytic system consists of Co(II) complex@ZnO exhibits potent antimicrobial activity and efficient solar-induced wastewater remediation. (August 2018)

• Record Type: Journal Article
• Authors: Essawy, Amr A.; Nassar, Amr M.; Arafa, Wael A.A.
• Is Part Of: Solar energy. Volume 170(2018)
• Page Start: 388
• Page End: 397
• Publication Date: 2018-08
• Subjects: Cobalt complex -- ZnO -- Photosensitization -- Photoredox mediator -- Photocatalysis; Solar energy -- Periodicals; Solar engines -- Periodicals; 621.47
• DOI: 10.1016/j.solener.2018.05.073
• Languages: English
• ISSNs: 0038-092X

Abstract

Graphical abstract: Highlights: Novel Co-complex was prepared and loaded on ZnO without affecting crystallinity. Loading Co-complex improves the photoresponse to visible part of solar-irradiation. Scavenging of h + and e − infers their participation in the photodegrdation reaction. Co-complex acts as redox mediator revealing prohibition of charges recombination. More OH and O2 − are produced giving higher photcatalytic rate in degrading MB. Abstract: Recently, cobalt complexes have been engaged in contemporary scientific prospects. Thus, this work presents the synthesis of novel cobalt(II) complex (Co2 L) from Schiff base ligand, N, N'-bis-(5-methoxysalicylidene)-trans-(1, 4-cyclohexylenediamine) (H2 L) and investigates its synergistically catalytic characteristics along with ZnO photocatalyst via synthesis of novel composite Co2 L/ZnO. The as-synthesized substances were characterized using FT-IR, UV/vis., TGA, XRD, and TEM. Co2 L shows impressive antimicrobial properties compared to a typical antibacterial and antifungal agents, tetracycline and amphotericin B, respectively. The results confirmed that, the loaded cobalt complex photosensitizes ZnO augmenting its solar response and acts as redox mediator revealing marvelous reduction of electrons and holes recombination. Compared with bare ZnO, Co2 L/ZnO composite exhibited better photocatalytic degradation of methylene blue under solar-irradiation within degradation efficiency 97.7%. The developed composite provides integrity of the optical and structural characteristics. Moreover, it articulates new insights towards the synthesis of low cost, highly stable, and efficient photocatalyst for wastewater remediation.