In situ transmission electron microscopy study and molecular dynamics simulation of dislocation loop evolution in FeCrAl alloys under Fe+ irradiation. (September 2021)

• Record Type: Journal Article
• Authors: Li, Y.P.; Yu, M.S.; Ran, G.; Gao, N.; Chen, Y.; Han, Q.; Wang, H.; Zhou, Z.H.; Huang, J.C.
• Is Part Of: Materials today energy. Volume 21(2021)
• Publication Date: 2021-09
• Subjects: In situ TEM observation -- Loop reaction -- Molecular dynamics simulation -- Fuel cladding -- Irradiation damage; Energy development -- Periodicals; Energy industries -- Periodicals; Power resources -- Periodicals; Energy policy -- Periodicals; Energy development; Energy industries; Energy policy; Power resources; Electronic journals; Periodicals; 621.042
• DOI: 10.1016/j.mtener.2021.100788
• Languages: English
• ISSNs: 2468-6069

Abstract

Abstract: FeCrAl alloys with excellent comprehensive properties are the most promising candidates to replace zirconium alloy fuel claddings. In our study, the dislocation loop evolution including initiation, migration, merging, growth, annihilation, and reaction in a FeCrAl alloy was investigated by using in situ transmission electron microscopy during 400 keV Fe + irradiation. The mechanism induced the growth of dislocation loops including the absorption of high-mobility point defects and defect clusters and the merging of two or more dislocation loops of different sizes. In the initial stage of irradiation, the loop density was relatively stable and the loop size increased rapidly with the increase in irradiation dose; however, owing to the formation of dislocation networks, the loop density decreased significantly in the later stage of irradiation. Both b = 1/2<111> and b = <100> dislocation loops were formed in the FeCrAl alloy. The ratio of <100> loops was 49% after irradiation with 0.14 dpa at 723 K. Molecular dynamics simulations displayed the reaction of dislocation loops with different Burgers vectors and sizes. Although the presence of alloying elements (Cr and Al) would prohibit or delay the interaction process, loop merging continued owing to the atomic rearrangement of dislocation loops. Graphical abstract: Image 1 Highlights: The loop evolution in FeCrAl alloy was real time in situ analyzed during Fe + irradiation. Two growth mechanisms of dislocation loops were obtained and deeply discussed. The interaction between 1/2<111> loop and <100> loop was observed by in situ transmission electron microscopy and simulated by molecular dynamics. Small loops could be absorbed by large loops, resulting in the loop growth. The atomic rearrangement of dislocation loops during the interactions was explored.