Interfacial engineering in 3D/2D and 1D/2D bismuth ferrite (BiFeO3)/Graphene oxide nanocomposites for the enhanced photocatalytic activities under sunlight. (December 2021)

• Record Type: Journal Article
• Authors: Bharathkumar, S.; Sakar, M.; Archana, J.; Navaneethan, M.; Balakumar, S.
• Is Part Of: Chemosphere. Volume 284(2021)
• Publication Date: 2021-12
• Subjects: Multiferroics -- Bismuth ferrite -- Graphene oxide -- Nanostructures -- Photocatalysis -- Ultrasonic-process -- Interface engineering; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2021.131280
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: 3D-particulate and 1D-fiber structures of multiferroic bismuth ferrite (BiFeO3 /BFO) and their composites with 2D-graphene oxide (GO) have been developed to exploit the different scheme of interfacial engineering as 3D/2D and 1D/2D systems. Particulates and fibers of BFO were developed via sol-gel and electrospinning fabrication approaches respectively and their integration with GO was performed via the ultrasonic-assisted chemical reduction process. The crystalline and phase formation of BiFeO3 and GO was confirmed from the XRD patterns obtained. The electron microscopic images revealed the characteristic integration of 3D particulates (with average size of 100 nm) and 1D fibers (with diameter of ~150 nm and few μm length) onto the 2D GO layers (thickness of ~27 nm). XPS analysis revealed that the BFO nanostructures have been integrated onto the GO through chemisorptions process, where it indicated that the ultrasonic process engineers the interface through the chemical modification of the surface of these 3D/2D and 1D/2D nanostructures. The photophysical studies such as the impedance and photocurrent measurements showed that the charge separation and recombination resistance is significantly enhanced in the system, which can directly be attributed to the effective interfacial engineering in the developed hetero-morphological composites. The degradation studies against a model pollutant Rhodamine B revealed that the developed nanocomposites exhibit superior photocatalytic activity via the effective generation of OH radicals as confirmed by the radical analysis studies (100% degradation in 150 and 90 min for 15% GO/BFO particulate and fiber composites, respectively). The developed system also demonstrated excellent photocatalytic recyclability, indicated their enhanced stability. Graphical abstract: Image 1 Highlights: Fabrication of graphene oxide integrated BiFeO3 particulate & fiber composites. Study on the sunlight driven photocatalytic efficiency of the materials. Achievement of 100% degradation of RhB dye in 90 min over 15 wt% GO-BFO fibers. Proposition of photocatalytic mechanism via photophysical studies on samples.