Recent advances in the flame retardancy role of graphene and its derivatives in epoxy resin materials. (October 2021)

• Record Type: Journal Article
• Authors: Liu, Quanyi; Zhao, Yinlong; Gao, Shansong; Yang, Xiong; Fan, Rong; Zhi, Maoyong; Fu, Ming
• Is Part Of: Composites. Volume 149(2021)
• Publication Date: 2021-10
• Subjects: A. Graphene -- A. Resins -- B. Flame retardancy -- Preparation method; APP Ammonium polyphosphate -- APTES 3-amino-propyltriethoxy-silane -- C60 Fullerene -- CCT Cone calorimetry test -- CTAB Hexadecyltrimethylammonium bromide -- DGEBA Diglycidyl ether of bisphenol A -- DNA Deoxyribonucleic acid -- DOPO 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide -- DPPES 2-(diphenylphosphino)ethyltriethoxy silane -- E-44 A typeof epoxy resin -- EP Epoxy resin -- EP-51 A type of epoxyresin -- FRGO Functionalized graphene oxide -- GMA Glycidyl methacrylate -- GnPD DNA functionalized graphene -- GNS/GNSs Graphene nanosheets -- GO Graphene oxide -- GO-MD-MP A hybrid flame retardant -- GOMT Hosphorus-nitrogen functionalized GO -- GON Graphene oxide nanosheets -- HCCP Hexachlorocyclotriphosphazene -- HNT Halloysite -- ZHS Zinc hydroxystannate -- JY-256 A type of epoxy resin -- LOI Limiting oxygen index -- M2070 JEFFAMINE polyether amine -- MA Maleic anhydride -- MCC Micro ccombustion calorimetry -- MCM-41 Mobil Composition Of Matter No. 41 -- m-GNSs Modified graphene nanosheets -- MGO Modified graphene oxide -- MOF Metal-organic framework -- MZF Mesoporous zinc ferrate -- OGPOSS Octa (propyl glycidyl ether) polyhedral oligosilsesquioxane -- PA Phytic acid -- PDPG PbisDOPOMA-POSSMA-GMA -- PEI Polyethlyamine -- PHRR Peak heat release rate -- PiP Piperazine -- POSS polyhedral oligosilsesquioxane -- PPA Polyphosphamide -- PPGO Piperazine and phytic acid functionalized GO -- RGO Reduction graphene oxide -- s-Al2O3 Spherical aluminum oxide -- SBA-15 Mesoporous silica -- TEOS Tetraethylorthosilicate -- TGA Thermogravimetric analysis -- TGIC 1, 3, 5-triglycidyl isocyanurate -- THR Total heat release -- TSP Total smoke production -- TSR Total smoke release -- VTES Vinyltriethoxysilane -- YDF-170 Diglycidyl ether of bisphenol-F epoxy -- ZIF-67/RGO-B Functionalized reduced graphene oxide with Co-ZIF (zeolitic imidazolate frameworks-67) adsorbed borate ions -- ZIF-8 Zeolitic imidazolate frameworks-8 -- α-ZrP α-zirconium phosphate; Composite materials -- Periodicals; Manufacturing processes -- Periodicals; Composite materials; Manufacturing processes; Periodicals; 620.11805
• DOI: 10.1016/j.compositesa.2021.106539
• Languages: English
• ISSNs: 1359-835X

Abstract

Abstract: Epoxy resin has been widely used in aerospace, automotive construction and other fields due to its excellent mechanical performance, dielectric and corrosion resistance properties. However, epoxy resin can burn easily in the air and create the massive hazardous smoke and toxic gases during combustion, which may bring casualties and property losses, and limit its range of usage. It is therefore necessary to improve its flame retardant performance by using various flame retardants. Graphene and its derivatives have unique lamellar structure and can endow epoxy resin with good flame retardancy properties through the barrier effect of "tortuous path". In this wok, the recent research progress of graphene and its derivatives flame-retardant epoxy resin, and flame-retardant mechanism were systematically introduced. Moreover, the problems faced by flame-retardant epoxy resin and its development prospects have been analyzed. We hope that this review can provide valuable reference and inspiration for the researchers in this field.