Tetrafluoroborate‐Induced Reduction in Defect Density in Hybrid Perovskites through Halide Management. Issue 32 (4th July 2021)

• Record Type: Journal Article
• Authors: Nagane, Satyawan; Macpherson, Stuart; Hope, Michael A.; Kubicki, Dominik J.; Li, Weiwei; Verma, Sachin Dev; Ferrer Orri, Jordi; Chiang, Yu‐Hsien; MacManus‐Driscoll, Judith L.; Grey, Clare P.; Stranks, Samuel D.
• Is Part Of: Advanced materials. Volume 33:Issue 32(2021)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2021-07-04
• Subjects: charge‐carrier recombination -- defects -- perovskite solar cells -- photoluminescence -- surface treatment -- tetrafluoroborate; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.202102462
• Languages: English
• ISSNs: 0935-9648

Abstract

Abstract: Hybrid‐perovskite‐based optoelectronic devices are demonstrating unprecedented growth in performance, and defect passivation approaches are highly promising routes to further improve properties. Here, the effect of the molecular ion BF4 −, introduced via methylammonium tetrafluoroborate (MABF4 ) in a surface treatment for MAPbI3 perovskite, is reported. Optical spectroscopy characterization shows that the introduction of tetrafluoroborate leads to reduced non‐radiative charge‐carrier recombination with a reduction in first‐order recombination rate from 6.5 × 10 6 to 2.5 × 10 5 s −1 in BF4 − ‐treated samples, and a consequent increase in photoluminescence quantum yield by an order of magnitude (from 0.5 to 10.4%). 19 F, 11 B, and 14 N solid‐state NMR is used to elucidate the atomic‐level mechanism of the BF4 − additive‐induced improvements, revealing that the BF4 − acts as a scavenger of excess MAI by forming MAI–MABF4 cocrystals. This shifts the equilibrium of iodide concentration in the perovskite phase, thereby reducing the concentration of interstitial iodide defects that act as deep traps and non‐radiative recombination centers. These collective results allow us to elucidate the microscopic mechanism of action of BF4 − . Abstract : The surface treatment of MAPbI3 through methylammonium tetrafluoroborate (MABF4 ) leads to reduced non‐radiative charge‐carrier recombination with a reduction in first‐order recombination rate by an order of magnitude. Solid‐state NMR is used to elucidate the atomic‐level mechanism of the BF4 − ‐additive‐induced improvements, revealing that it can act as a scavenger of excess methylammonium iodide (MAI).