Porous Anionic Co(II) Metal‐Organic Framework, with a High Density of Amino Groups, as a Superior Luminescent Sensor for Turn‐on Al(III) Detection. Issue 46 (6th July 2021)

• Record Type: Journal Article
• Authors: Chand, Santanu; Verma, Gaurav; Pal, Arun; Pal, Shyam Chand; Ma, Shengqian; Das, Madhab C.
• Is Part Of: Chemistry. Volume 27:Issue 46(2021)
• Page Start: 11804
• Page End: 11810
• Publication Date: 2021-07-06
• Subjects: Aluminium -- anionic -- luminescence -- sensors -- metal-organic frameworks; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.202101692
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract: Accumulation of high concentrations of Al(III) in body has a direct impact on health and therefore, the trace detection of Al(III) has been a matter for substantial concern. An anionic metal organic framework ({[Me2 NH2 ]0.5 [Co(DATRz)0.5 (NH2 BDC)] ⋅ xG} n ; 1 ; HDATRz=3, 5‐diamino‐1, 2, 4‐triazole, H2 NH2 ‐BDC=2‐amino‐1, 4‐benzenedicarboxylic acid, G=guest molecule) composed of two types of secondary building units (SBU) and channels of varying sizes was synthesized by employing a rational design mixed ligand synthesis approach. Free −NH2 groups on both the ligands are immobilized onto the pore surface of the MOF which acts as a superior luminescent sensor for turn‐on Al(III) detection. Furthermore, the large channels could allow the counter‐ions to pass through and get exchanged to selectively detect Al(III) in presence of other seventeen metal ions with magnificent luminescence enhancement. The observed limit of detection is as low as 17.5 ppb, which is the lowest among the MOF‐based sensors achieved so far. To make this detection approach simple, portable and economic, we demonstrate MOF filter paper test for real time naked eye observation. Abstract : Al3+ sensor : A 3D porous anionic MOF displays superior turn‐on sensing for Al(III) ions with ultralow sensitivity resulted from stronger interactions with free amines by employing strategic design principle. The detection approach is simple, fast, portable and economic as demonstrated by MOF filter paper tests for naked eye observation.