Nanocatalosomes as Plasmonic Bilayer Shells with Interlayer Catalytic Nanospaces for Solar‐Light‐Induced Reactions. (30th April 2020)

• Record Type: Journal Article
• Authors: Kumar, Amit; Kumari, Nitee; Dubbu, Sateesh; Kumar, Sumit; Kwon, Taewan; Koo, Jung Hun; Lim, Jongwon; Kim, Inki; Cho, Yoon‐Kyoung; Rho, Junsuk; Lee, In Su
• Is Part Of: Angewandte Chemie. Volume 132:Number 24(2020)
• Page Start: 9547
• Page End: 9556
• Publication Date: 2020-04-30
• Subjects: bilayer structures -- nanocatalysts -- plasmonic-catalytic materials -- solar light -- Suzuki–Miyaura cross-coupling; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.202001531
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Interest and challenges remain in designing and synthesizing catalysts with nature‐like complexity at few‐nm scale to harness unprecedented functionalities by using sustainable solar light. We introduce "nanocatalosomes"—a bio‐inspired bilayer‐vesicular design of nanoreactor with metallic bilayer shell‐in‐shell structure, having numerous controllable confined cavities within few‐nm interlayer space, customizable with different noble metals. The intershell‐confined plasmonically coupled hot‐nanospaces within the few‐nm cavities play a pivotal role in harnessing catalytic effects for various organic transformations, as demonstrated by "acceptorless dehydrogenation", "Suzuki–Miyaura cross‐coupling" and "alkynyl annulation" affording clean conversions and turnover frequencies (TOFs) at least one order of magnitude higher than state‐of‐the‐art Au‐nanorod‐based plasmonic catalysts. This work paves the way towards next‐generation nanoreactors for chemical transformations with solar energy. Abstract : Catalytic cavities : „Nanocatalosomes" are a bio‐inspired bilayer‐vesicular design of nanoreactors with hollow metallic‐bilayer shells. The few‐nm intershell nanospaces can be controlled and customized with different noble metals to generate numerous interlayer‐confined catalytically active cavities harnessing combined plasmonic–catalytic effects and performing highly efficient solar‐light‐induced organic reactions with unprecedented rates.