Surface carboxyl-activated polyester (PET) fibers decorated with glucose carbon microspheres and their enhanced selective adsorption for dyes. (December 2018)

• Record Type: Journal Article
• Authors: Meng, Lu; Xu, Xiaohui; Bai, Bo; Ma, Meiling; Li, Shan; Hu, Na; Wang, Honglun; Suo, Yourui
• Is Part Of: Journal of physics and chemistry of solids. Volume 123(2018)
• Page Start: 378
• Page End: 388
• Publication Date: 2018-12
• Subjects: Carbon microspheres -- Polyester (PET) fibers -- Selective adsorption -- Hydrothermal carbonization -- Regeneration; Solids -- Periodicals; Solides -- Périodiques; Solids; Periodicals; 530.41
• DOI: 10.1016/j.jpcs.2018.08.005
• Languages: English
• ISSNs: 0022-3697

Abstract

Abstract: Glucose carbon microspheres have been widely used for wastewater treatment as adsorbent owing to their strong adsorption capacity, but for large-scale applications, the glucose carbon microspheres are inconvenient to be recycled from aqueous suspension due to their good suspendability. Moreover, the primitive nature of small particle size, large specific surface area and high surface energy of glucose carbon microspheres make them prone to aggregate and thus, disperse no-effectively for the other extended application. To solve this dilemma, polyester (PET) fibers decorated with glucose carbon microspheres (GC@PFs) were herein fabricated by one-step hydrothermal carbonization with acrylic acid as a coupling agent. The products were characterized by Fourier Transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), Boehm titration, X-ray diffraction (XRD), Thermo-gravimetric Analysis (TG), Scanning Electron Microscope (SEM) and zeta potential respectively. The experimental results showed that a large amount of glucose carbon microspheres were evenly dispersed on the surface of carboxyl activated polyester fibers with uniform particle diameter, and the composite fibers showed desirable adsorption ability of cationic dyes for its more negative zeta potential. The dye adsorption isotherm follows Langmuir model and pseudo-second-order kinetic model better. Remarkably, the adsorbent has an excellent recyclability for maintaining a high removal rate (>85%) to dye even after 10 cycles. Highlights: Glucose carbon microspheres were evenly distributed on the PET fibers surface that solved the problem of easy aggregation. The polyester fibers were firstly decorated with glucose carbon microspheres through one-step hydrothermal carbonization. Acrylic acid maintained the integrity of PET fabric and introduced a quite number of carboxyl groups on the PET surface. The surface decorated composite material possessed good adsorption property and easy recovery performance. The glucose carbon microspheres decorated polyester fibers showed a highly selective adsorption for the cationic dyes.