Self‐assembled Pd nanoparticle‐containing ionic liquid: Efficient and reusable catalyst for the Heck reaction in water. (30th March 2017)

• Record Type: Journal Article
• Authors: Zong, Yingxiao; Wang, Junke; An, Pengli; Yue, Guoren; Pan, Yi; Wang, Xicun
• Is Part Of: Applied organometallic chemistry. Volume 31:Number 11(2017:Nov.)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2017-03-30
• Subjects: C—C coupling -- Heck reaction -- ionic liquid -- nanoparticle -- palladium; Organometallic chemistry -- Periodicals; Organometallic compounds -- Periodicals; 547.05
• DOI: 10.1002/aoc.3762
• Languages: English
• ISSNs: 0268-2605

Abstract

Abstract : A self‐assembled Pd nanoparticle‐containing ionic liquid as metal–organic polymer was successfully prepared. The structure of the catalyst was characterized using Fourier transform infrared and 1 H NMR spectroscopies, scanning electron microscopy and elemental analysis. The catalyst was effectively employed in the palladium‐catalyzed Heck reaction in water as a green solvent. Moreover, due to its stability the catalyst can be recovered simply and effectively and reused nine times without much loss of activity. Abstract : A self‐assembled Pd nanoparticle‐containing ionic liquid as metal–organic polymer was successfully prepared. The structure of the catalyst was characterized. The catalyst was effectively employed in the palladium‐catalyzed Heck reaction in water as a green solvent. Moreover, due to its stability the catalyst can be recovered simply and effectively and reused nine times without much activity loss.