Metal–Organic Frameworks: Boosting Catalysis of Pd Nanoparticles in MOFs by Pore Wall Engineering: The Roles of Electron Transfer and Adsorption Energy (Adv. Mater. 30/2020). Issue 30 (28th July 2020)

• Record Type: Journal Article
• Authors: Chen, Dongxiao; Yang, Weijie; Jiao, Long; Li, Luyan; Yu, Shu‐Hong; Jiang, Hai‐Long
• Is Part Of: Advanced materials. Volume 32:Issue 30(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-07-28
• Subjects: adsorption energy -- electron transfer -- metal nanoparticles -- metal–organic frameworks -- microenvironment regulation; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.202070225
• Languages: English
• ISSNs: 0935-9648

Abstract

Abstract : The isoreticular metal–organic framework (MOF) UiO‐66‐X with diverse functional groups, encapsulating guest Pd nanoparticles, is fabricated by H.‐L. Jiang and co‐workers, as described in article number 2000041 . The chemical microenvironment around the Pd is systematically regulated by these MOF hosts, giving rise to distinctly different performances toward the hydrogenation of benzoic acid.