Dielectric, thermal and Raman spectroscopy studies of lead-free (Na0.5Bi0.5)1−xSrxTiO3 (x = 0, 0.04 and 0.06) ceramics. (2nd August 2016)

• Record Type: Journal Article
• Authors: Suchanicz, J.; Bovtun, V.; Dutkiewicz, E.M.; Konieczny, K.; Sitko, D.; Kluczewska, K.; Wajda, A.; Kalvane, A.; Sternberg, A.
• Is Part Of: Phase transitions. Volume 89:Number 7/8(2016)
• Page Start: 856
• Page End: 862
• Publication Date: 2016-08-02
• Subjects: Thermal properties -- structural properties -- ferroelectric properties -- dielectric properties; Phase transformations (Statistical physics) -- Periodicals; 530.47405
• DOI: 10.1080/01411594.2016.1177825
• Languages: English
• ISSNs: 0141-1594

Abstract

ABSTRACT: Lead-free (Na0.5 Bi0.5 )1 − x Sr x TiO3 ( x = 0, 0.04 and 0.06) ceramics with relative densities above 97% were prepared by solid-state synthesis process. Their dielectric, thermal and Raman properties were studied. X-ray diffraction analysis shows perovskite structure with rhombohedral symmetry at room temperature. Sr doping of Na0.5 Bi0.5 TiO3 (NBT) results in an increase of the dielectric permittivity, diffusing of the permittivity maximum and its shift toward lower temperatures. The temperature of the rhombohedral–tetragonal phase transition indicated by the differential scanning calorimetry (DSC) peak and relaxational dielectric anomaly near the depolarization temperature are also shifted toward lower temperatures. The observed increase and broadening of the permittivity maximum, enhancement of the dielectric relaxation near the depolarization temperature, broadening of the DSC anomaly related to the rhombohedral–tetragonal phase transition and broadening of the Raman bands with increasing Sr content are attributed to the increase of the degree of cationic disorder and evident enhancement of the relaxor-like features in NBT– x ST. This enhancement could play a positive role in the improvement of the piezoelectric performance of NBT-based ceramics.