Direct enantiomeric discrimination through antisymmetric hyperfine coupling. Issue 67 (29th July 2021)
- Record Type:
- Journal Article
- Title:
- Direct enantiomeric discrimination through antisymmetric hyperfine coupling. Issue 67 (29th July 2021)
- Main Title:
- Direct enantiomeric discrimination through antisymmetric hyperfine coupling
- Authors:
- Garbacz, Piotr
Vaara, Juha - Abstract:
- Abstract : A chirality-sensitive effect induced by antisymmetric hyperfine coupling, which lifts the intrinsic insensitivity of electron paramagnetic resonance spectroscopy to molecular chirality, is described. Abstract : Chiral open-shell molecules possessing permanent electric dipole moments have an EPR signal at the difference frequency of the electron and nuclear resonances, allowing direct enantiomeric discrimination by signal phase. The effect depends on the vector antisymmetry of the hyperfine coupling. Quantum chemistry suggests chiral bisfluorene methyl radical derivatives as promising for experiments.
- Is Part Of:
- Chemical communications. Volume 57:Issue 67(2021)
- Journal:
- Chemical communications
- Issue:
- Volume 57:Issue 67(2021)
- Issue Display:
- Volume 57, Issue 67 (2021)
- Year:
- 2021
- Volume:
- 57
- Issue:
- 67
- Issue Sort Value:
- 2021-0057-0067-0000
- Page Start:
- 8264
- Page End:
- 8267
- Publication Date:
- 2021-07-29
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d1cc02579a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 18521.xml