Flow-electrochemical synthesis of Prussian Blue based nanozyme 'artificial peroxidase'. Issue 33 (17th August 2021)

• Record Type: Journal Article
• Authors: Komkova, Maria A.; Vetoshev, Kirill R.; Andreev, Egor A.; Karyakin, Arkady A.
• Is Part Of: Dalton transactions. Volume 50:Issue 33(2021)
• Page Start: 11385
• Page End: 11389
• Publication Date: 2021-08-17
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d1dt02107a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Fully electrochemical flow-through synthesis of Prussian Blue nanozymes that defeat peroxidase with a more than 200 times higher catalytic rate constant. Abstract : We report on fully electrochemical flow-through synthesis of Prussian Blue based nanozymes defeating peroxidase in terms of more than 200 times higher catalytic rate constant ( k appcat = 6 × 10 4 s −1 ). Being reagentless, reproducible, simple and scalable, the proposed approach blazes new trails for the electrosynthesis of functional conductive and electroactive nanomaterials.