Calcination‐Free Synthesis of Well‐Dispersed and Sub‐10 nm Spinel Ferrite Nanoparticles as High‐Performance Anode Materials for Lithium‐Ion Batteries: A Case Study of CoFe2O4. Issue 50 (22nd July 2021)

• Record Type: Journal Article
• Authors: Zhang, Yifan; Zhang, Yamin; Cao, Yi; Xie, Minghao; Li, Jiabao; Balzer, Alex; Liu, Nian; John Zhang, Z.
• Is Part Of: Chemistry. Volume 27:Issue 50(2021)
• Page Start: 12900
• Page End: 12909
• Publication Date: 2021-07-22
• Subjects: anode materials -- cobalt ferrites -- electrochemistry -- lithium-ion batteries -- materials science; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.202102098
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract: Spinel ferrites are promising anode materials for lithium‐ion batteries (LIBs) owing to their high theoretical specific capacities. However, their practical application is impeded by inherent low conductivity and severe volume expansion, which can be surpassed by increasing the surface‐to‐volume ratio of nanoparticles. Currently, most methods produce spinel ferrite nanoparticles with large size and severe aggregation, degrading their electrochemical performance. In this study, a low‐temperature aminolytic route was designed to synthesize sub‐10 nm CoFe2 O4 nanoparticles with good dispersion through carefully exploiting the reaction of acetates and oleylamine. The performance of CoFe2 O4 nanoparticles obtained by a traditional co‐precipitation method was also investigated for comparison. This work demonstrates that CoFe2 O4 nanoparticles synthesized by the aminolytic route are promising as anode materials for LIBs. Besides, this method can be extended to design other spinel ferrites for energy storage devices with superior performance by simply changing the starting material, such as MnFe2 O4, MgFe2 O4, ZnFe2 O4, and so on. Abstract : A low‐temperature aminolytic route was designed to synthesize sub‐10 nm CoFe2 O4 nanoparticles (CFO NPs) with good dispersion through carefully exploiting the reaction of acetates and oleylamine (OAm). The well‐dispersed 9.1 nm CFO NPs prepared by the aminolytic method exhibited excellent reversible capacity and superior cycling stability compared with those prepared by co‐precipitation method, and the performance could be further enhanced when the size of nanoparticles decreased to 3.4 nm.