On Borromean links and related structures. Issue 5 (29th July 2021)

• Record Type: Journal Article
• Authors: O'Keeffe, Michael; Treacy, Michael M. J.
• Is Part Of: Acta crystallographica. Volume 77:Issue 5(2021)
• Page Start: 379
• Page End: 391
• Publication Date: 2021-07-29
• Subjects: Borromean rings -- n‐Borromean -- isonemal -- piecewise‐linear embedding; Crystallography -- Periodicals; Condensed matter -- Periodicals; 548
• DOI: 10.1107/S2053273321005568
• Languages: English
• ISSNs: 2053-2733

Abstract

Abstract : Descriptions are given of optimal piecewise‐linear embeddings of families of Borromean structures that can be generated by rotoinversion point‐group symmetries. These serve as templates for designed synthesis of polycatenanes. Abstract : The creation of knotted, woven and linked molecular structures is an exciting and growing field in synthetic chemistry. Presented here is a description of an extended family of structures related to the classical `Borromean rings', in which no two rings are directly linked. These structures may serve as templates for the designed synthesis of Borromean polycatenanes. Links of n components in which no two are directly linked are termed ` n ‐Borromean' [Liang & Mislow (1994). J. Math. Chem. 16, 27–35]. In the classic Borromean rings the components are three rings (closed loops). More generally, they may be a finite number of periodic objects such as graphs (nets), or sets of strings related by translations as in periodic chain mail. It has been shown [Chamberland & Herman (2015). Math. Intelligencer, 37, 20–25] that the linking patterns can be described by complete directed graphs (known as tournaments) and those up to 13 vertices that are vertex‐transitive are enumerated. In turn, these lead to ring‐transitive (isonemal) n ‐Borromean rings. Optimal piecewise‐linear embeddings of such structures are given in their highest‐symmetry point groups. In particular, isonemal embeddings with rotoinversion symmetry are described for three, five, six, seven, nine, ten, 11, 13 and 14 rings. Piecewise‐linear embeddings are also given of isonemal 1‐ and 2‐periodic polycatenanes (chains and chain mail) in their highest‐symmetry setting. Also the linking of n ‐Borromean sets of interleaved honeycomb nets is described.