Cover Feature: Fine Tunable, Redox Active Octapalladium Chains Supported by Linear Tetraphosphines, Leading to Dynamically 1D Self‐Assembled Coordination Polymers (Chem. Eur. J. 47/2021). Issue 47 (30th July 2021)

• Record Type: Journal Article
• Authors: Tanase, Tomoaki; Nakamae, Kanako; Miyano, Haruka; Ura, Yasuyuki; Kitagawa, Yasutaka; Yada, Shiho; Yoshimura, Tomokazu; Nakajima, Takayuki
• Is Part Of: Chemistry. Volume 27:Issue 47(2021)
• Page Start: 12010
• Page End: 12010
• Publication Date: 2021-07-30
• Subjects: 1D dynamic coordination polymer -- noncovalent interactions -- palladium chain complexes -- redox active metal chains -- tetraphosphine; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.202102416
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract : Dynamically 1D assembled linear Pd8 chains with bisisocyanide linkers are shown against a backdrop of contrails lit from below by the rising sun. A variety of Pd8 chains with a linear tetraphosphine, meso ‐dpmppm, were synthesized through both covalent and noncovalent interactions between two Pd4 fragments. They exhibited fine‐tunable electronic states, a wide range of redox properties, and dynamic 1D self‐assembly in solution. These findings could lead to the next frontier in exploring new functions with dynamically aggregated metal building blocks. More information can be found in the Full Paper by T. Tanase et al. (DOI: 10.1002/chem.202101715 ).