Antimony diiminopyridine complexes. Issue 34 (18th August 2021)

• Record Type: Journal Article
• Authors: Tidwell, John R.; Dutton, Jason L.; Martin, Caleb D.
• Is Part Of: Dalton transactions. Volume 50:Issue 34(2021)
• Page Start: 11716
• Page End: 11719
• Publication Date: 2021-08-18
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d1dt02085d
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The stoichiometric reactions of antimony trichloride, trimethylsilyl trifluoromethanesulfonate, and diiminopyridine ligands lead to the formation of the first antimony diiminopyridine complexes. Abstract : The stoichiometric reactions of antimony trichloride, trimethylsilyl trifluoromethanesulfonate, and diiminopyridine ligands lead to the formation of N, N ′, N ′′-chelated SbCl2 cationic complexes. Methyl and phenyl substituents on the imine carbons of the ligand yielded structures with a lone pair on antimony and the hydrogen substituted variant was notably different as it forms a Menshutkin complex with meta -xylene in the solid-state.