Experimental and DFT study of natural curcumin derived dyes as n-type sensitizers. (1st September 2021)

• Record Type: Journal Article
• Authors: Zarate, Ximena; González P, Ivan; Caramori, Stefano; Benazzi, Elisabetta; Barra, Tomas; Arrue, Lily; Wu, Yi-nan; Díaz-Uribe, Carlos; Vallejo, William; Schott, Eduardo
• Is Part Of: Solar energy. Volume 225(2021)
• Page Start: 305
• Page End: 315
• Publication Date: 2021-09-01
• Subjects: Curcumin dyes -- DSSC -- DFT -- EDDM -- IPCE -- APCE; Solar energy -- Periodicals; Solar engines -- Periodicals; 621.47
• DOI: 10.1016/j.solener.2021.06.051
• Languages: English
• ISSNs: 0038-092X

Abstract

Highlights: four different bio-inspired curcumin dyes. n-type sensitizers in regenerative TiO2 based photoelectrochemical cells. photoelectrochemical measurements were combined with quantum chemical computations. the best dye is 1, 7-bis-[4-hydroxy-3-methoxy-phenyl]-1, 6-heptadiene-3, 5-dione (curcumin) Abstract: In this paper, four different bio-inspired curcumin dyes were explored as n-type sensitizers in regenerative TiO2 based photoelectrochemical cells in order to rationalize their structure/performance relationships for solar energy conversion. To this end, photoelectrochemical measurements were combined with quantum chemical computations in order to adress curcumin binding mode to the semiconductor and the consequent effects on their electronic structure. In our conditions, it was found that the best conversion efficiency of the solar cell fabricated using 1, 7-bis-[4-hydroxy-3-methoxy-phenyl]-1, 6-heptadiene-3, 5-dione (curcumin) was 1.0%.