Systematic comparison of various oxidation treatments on diamond surface. (September 2021)

• Record Type: Journal Article
• Authors: Li, Chenxi; Zhang, Xiang; Oliveira, Eliezer F.; Puthirath, Anand B.; Neupane, Mahesh R.; Weil, James D.; Birdwell, A. Glen; Ivanov, Tony G.; Kong, Seoyun; Gray, Tia; Kannan, Harikishan; Biswas, Abhijit; Vajtai, Robert; Galvao, Douglas S.; Ajayan, Pulickel M.
• Is Part Of: Carbon. Volume 182(2021)
• Page Start: 725
• Page End: 734
• Publication Date: 2021-09
• Subjects: Diamond oxidation -- Diamond powder -- Polycrystalline diamond film -- Molecular mechanics simulations; Carbon -- Periodicals; Carbone -- Périodiques; Koolstof; Toepassingen; Electronic journals; 546.681
• DOI: 10.1016/j.carbon.2021.06.050
• Languages: English
• ISSNs: 0008-6223

Abstract

Abstract: It is known that surface terminations contribute significantly to diamond properties. As one of the most commonly studied types, oxygen-terminated diamond surface possesses a positive electron affinity (PEA) and hydrophilicity, making it suitable for electronic device fabrication and bioapplications. Various oxidation methods have been reported on diamond, but a systematic comparison is still lacking. Herein, we present a comparative study on the oxidation of microcrystalline diamond powder (DP) and polycrystalline diamond film (PCD) by wet chemical treatments, including various acid mixtures, as well as by dry processes, including O2 plasma and UV ozone. X-ray photoelectron spectroscopy (XPS) and Fourier-transform infrared spectroscopy (FTIR) results reveal that H2 SO4 /HNO3 5:1 at 360 °C demonstrates the best oxidation performance on DP and PCD compared to other wet chemical methods, while the PCD treated by O2 plasma exhibits the highest oxygen content among all the treated samples. Besides, the concentration of carbon-oxygen groups on diamond surfaces is found largely determined by oxidation methods. These experimental results can be attributed to the corresponding oxidation mechanism of different treatments and agree well with theoretical simulations. Finally, we investigated the sp 2 bonded carbon concentration and surface roughness of oxidized PCD, suggesting the optimized diamond surface cleaning conditions. Graphical abstract: Image 1 Highlights: This work provides a comprehensive and comparative analysis of diamond surface oxidation by various wet and dry methods. Various oxidation treatments produce different degrees of oxidation as well as distinct proportions of oxygenated groups. The influence of oxidation treatment on graphitization degree and surface morphology of diamond has been compared. The experimental results can be well explained by molecular mechanical (MM) simulations.