Bio-based process for the catalytic production of ethyl levulinate from cellulose. (15th October 2021)

• Record Type: Journal Article
• Authors: Kim, Juyeon; Han, Jeehoon
• Is Part Of: Applied energy. Volume 300(2021)
• Publication Date: 2021-10-15
• Subjects: Catalytic process -- Techno-economics -- Energy integration -- Process design -- Ethanol -- Ethyl levulinate; LA Levulinic acid -- EL Ethyl levulinate -- EtOH Ethanol -- HMF Hydroxymethylfurfural -- C6 Cellulose -- H2SO4 Sulfuric acid -- VLE Vapor–liquid equilibrium -- MSP Minimum selling price -- NRTL Non-random two liquid -- HEN Heat exchanger network -- ACC Annualized capital costs -- AOC Annualized operating costs; Power (Mechanics) -- Periodicals; Energy conservation -- Periodicals; Energy conversion -- Periodicals; 621.042
• DOI: 10.1016/j.apenergy.2021.117430
• Languages: English
• ISSNs: 0306-2619

Abstract

Highlights: A novel process for ethyl levulinate production from cellulose is proposed. Large-scale process simulation is performed based on experimental data. Techno-economic analysis of the process is conducted. Abstract: This paper presents a bio-based process for the catalytic conversion of cellulose to ethyl levulinate and an analysis of its techno-economic feasibility. The said bio-based process relies as major feedstock on cellulose, which can be derived from lignocellulosic biomass. cellulose is converted to ethyl levulinate via a homogeneous catalytic reaction whereby dilute sulfuric acid in combination with Al salts is the catalyst and ethanol is the solvent and reactant. This approach affords high ethyl levulinate yields but requires complex procedures for used catalyst and solvent recycling. Based on experimental results on the homogeneous catalytic reaction and vapor–liquid equilibrium separation in the previous studies, a simulation was conducted that included process design, energy integration, and economic analysis. Results from this simulation indicated the proposed bio-based process to afford a minimum selling price of US$ 2, 830 per ton of ethyl levulinate, which was highly dependent on an off-site supply of heating energy required for ethanol purification. 1