Effect of Polyvinyl Alcohol on the Growth, Structure, Morphology, and Electrical Conductivity of Polypyrrole Nanoparticles Synthesized via Microemulsion Polymerization. (24th September 2012)

• Record Type: Journal Article
• Authors: Krishna, Anurag; Kumar, Amit; Singh, Rajiv Kumar
• Other Names: Kajbafvala A. Academic Editor.; Panchapakesan B. Academic Editor.; Sorrentino A. Academic Editor.; Wang C. Academic Editor.
• Is Part Of: ISRN nanomaterials. Volume 2012(2012)
• Publication Date: 2012-09-24
• Subjects: Nanostructured materials -- Periodicals; Nanostructured materials; Electronic journals; Periodicals; 620.115
• DOI: 10.5402/2012/809063
• Languages: English
• ISSNs: 2090-8741

Abstract

Abstract : Polypyrrole (PPy) nanoparticles were synthesized via microemulsion polymerization technique using sodium dodecyl sulfate as surfactant. Polyvinyl alcohol (PVA) was added as soft template during polymerization to modify the structure and properties of PPy nanoparticles. The synthesized materials namely, PVA-free and PVA added were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and DC electrical conductivity measurements. The sample synthesized in the presence of PVA has longer conjugation length as estimated from FT-IR investigation. Temperature dependence (4.2–300 K) of DC electrical conductivity measurement reveals that the PVA has a strong effect on the polymerization mechanism of PPy giving evidence of H-bonded assistance during polymerization leading to the synthesis of better ordered polymer. A growth mechanism has been proposed which explains the H-bonded assistance of PPy polymerization leading to enhanced structural ordering.