1D interconnected porous binary transition metal phosphide nanowires for high performance hybrid supercapacitors. (19th May 2021)

• Record Type: Journal Article
• Authors: Sivakumar, Periyasamy; Jung, Min Gyu; Raj, C. Justin; Rana, Harpalsinh H.; Park, Ho Seok
• Is Part Of: International journal of energy research. Volume 45:Number 11(2021)
• Page Start: 17005
• Page End: 17014
• Publication Date: 2021-05-19
• Subjects: 1D nanowire -- battery‐type electrode -- bimetallic phosphide -- high capacity -- hybrid supercapacitor; Power resources -- Periodicals; Power (Mechanics) -- Periodicals; Power resources -- Research -- Periodicals; 621.042
• DOI: 10.1002/er.6874
• Languages: English
• ISSNs: 0363-907X

Abstract

Summary: The one‐dimensional (1D) nanostructured battery‐type electrode materials are considered as a promising candidate to develop high energy hybrid supercapacitors (HSCs) owing to their reversible and abundant redox activity. Herein, we report 1D nickel cobalt phosphide (NCP) wire‐like nanoarchitecture, which is prepared by hydrothermal method and subsequent phosphorization treatment. The 1D interconnected porous NCP nanowires are featured with the rich exposed redox active sites and fast charge transport pathway for high‐capacity battery‐type electrodes. The bimetallic NCP electrode exhibits a larger specific capacitance of 1395 F g −1 than those of monometallic nickel phosphide (920 F g −1 ) and cobalt phosphide (568 F g −1 ) electrodes at 1 A g −1 . The HSCs are constructed using bimetallic 1D NCP nanowires and the activated carbon as positive and negative electrodes, respectively. The resulting HSCs deliver the improved energy density of 53.31 W h kg −1 and power density of 46.53 kW kg −1 along with the capacitance retention of 83.04% over 20 000 cycles. Abstract : 1D interconnected porous bimetallic nickel cobalt phosphide wire‐like nanoarchitecture is featured with the abundant exposed redox active sites and fast charge transport pathway for high‐capacity battery‐type electrodes. The resulting hybrid supercapacitors deliver the improved energy density of 53.31 W h kg −1 and power density of 46.53 kW kg −1 along with the capacitance retention of 83.04% over 20 000 cycles.