Characterization of pruned tea branch biochar and the mechanisms underlying its adsorption for cadmium in aqueous solution. Issue 43 (6th August 2021)

• Record Type: Journal Article
• Authors: Han, Chuan; Wang, Miaofei; Ren, Yanfang; Zhang, Liming; Ji, Yu; Zhu, Wenjia; Song, Yaping; He, Junyu
• Is Part Of: RSC advances. Volume 11:Issue 43(2021)
• Page Start: 26832
• Page End: 26843
• Publication Date: 2021-08-06
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/d1ra04235a
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : In the present study, discarded pruned tea branch was used to prepare a new biochar, and the physicochemical properties and adsorption characteristics were investigated by characterization and batch experiments. Abstract : In the present study, discarded pruned tea branch was used to prepare a new biochar, and the physicochemical properties and adsorption characteristics were investigated by characterization and batch experiments. With increasing pyrolysis temperature from 400 to 800 °C, the yield, specific surface area, and acidic functional groups had significant differences. The optimum adsorption conditions were determined as pH = 6 and dosage of 2 g L −1 . The pseudo-second-order kinetic and Langmuir isothermal model could fit well to the adsorption data, which showed that the adsorption process was dominated by monolayer chemical adsorption. The highest adsorption property (74.04 mg g −1 ) was obtained by the pyrolysis of tea branch biochar (TBB) at 700 °C owing to the adsorption mechanisms, including surface complexation, precipitation, metal ion exchange, and Cd 2+ –π interaction. After five cycles of desorption, biochar still showed superior adsorption (80%). Hence, the TBB acted as a regenerable adsorbent for treating Cd 2+ -containing wastewater.