Organocatalytic aminocarbonylation of α, β-unsaturated ketones with N, N-dimethyl carbamoylsilane. (9th April 2021)
- Record Type:
- Journal Article
- Title:
- Organocatalytic aminocarbonylation of α, β-unsaturated ketones with N, N-dimethyl carbamoylsilane. (9th April 2021)
- Main Title:
- Organocatalytic aminocarbonylation of α, β-unsaturated ketones with N, N-dimethyl carbamoylsilane
- Authors:
- Yang, Shou-Shan
Ren, Ying-Zheng
Guo, Yu-Yu
Du, Guang-Fen
Cai, Zhi-Hua
He, Lin - Abstract:
- Abstract : Schwesinger's superbase can efficiently activate the Si–CONMe2 bond and initiate the aminocarbonylation of α, β-unsaturated ketones and N, N -dimethyl carbamoylsilane. Abstract : An organic superbase-catalyzed aminocarbonylation reaction of α, β-unsaturated ketones was reported. Under the catalysis of 10 mol% Schwesinger's superbase t -Bu-P4, a variety of enones and ynones reacted with N, N -dimethyl carbamoylsilane to afford α-siloxyamides or α-hydroxyamides in 56–82% yields.
- Is Part Of:
- New journal of chemistry. Volume 45:Number 16(2021)
- Journal:
- New journal of chemistry
- Issue:
- Volume 45:Number 16(2021)
- Issue Display:
- Volume 45, Issue 16 (2021)
- Year:
- 2021
- Volume:
- 45
- Issue:
- 16
- Issue Sort Value:
- 2021-0045-0016-0000
- Page Start:
- 7256
- Page End:
- 7260
- Publication Date:
- 2021-04-09
- Subjects:
- Chemistry -- Periodicals
Chimie -- Périodiques
540 - Journal URLs:
- http://www.rsc.org/ ↗
http://www.rsc.org/is/journals/current/newjchem/njc.htm ↗ - DOI:
- 10.1039/d1nj00782c ↗
- Languages:
- English
- ISSNs:
- 1144-0546
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 6084.319900
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 18359.xml