Deep‐red‐emitting SrLaLiTeO6: Mn4+ double perovskites: Correlation between Mn4+‐O2− bonding and photoluminescence. Issue 10 (3rd June 2021)

• Record Type: Journal Article
• Authors: Lal, Sariga C.; Naseemabeevi, Jawahar I.; Ganesanpotti, Subodh
• Is Part Of: Journal of the American Ceramic Society. Volume 104:Issue 10(2021)
• Page Start: 5293
• Page End: 5306
• Publication Date: 2021-06-03
• Subjects: covalence -- crystal field parameters -- light emitting diode -- Mn4+ emission -- optical materials properties -- perovskites -- phosphors -- plant growth LEDs -- redshift -- tellurium compounds; Ceramics -- Periodicals; 620.1405
• DOI: 10.1111/jace.17910
• Languages: English
• ISSNs: 0002-7820

Abstract

Abstract: Mn 4+ ‐activated deep red‐emitting SrLaLiTeO6 phosphors are investigated for indoor plant growth LED applications for the first time. The phosphors crystallize in monoclinic ( P 21 / n ) symmetry is isostructural with SrLaLiTeO6 host. B‐site substitution of Mn 4+ ions is confirmed from the redshift of high energy phonon modes in both Raman and IR spectra. The phosphor exhibited a far‐red emission centered at 696 nm corresponding to the 2 E g → 4 A 2g spin‐forbidden transition of the Mn 4+ ions. Approximate crystal field parameters depict the weak influence of neighboring ligand fields on Mn 4+ ions and the least covalence of Mn 4+ ‐ligand bonding compared to other double perovskite phosphors. Moreover, the phosphors exhibit excellent thermal stability with an activation energy of 0.23 eV. Phosphor parameters including CCT, color purity, and quantum yield are evaluated and their values meet the requirements of a red‐emitting phosphor for LED applications. Furthermore, the PL emission spectrum of SrLaLiTeO6 : Mn 4+ matches with the absorption spectrum of plant phytochromes denoting the prospects of this phosphor for indoor plant growth LED applications.