An evaluation of source apportionment of fine OC and PM2.5 by multiple methods: APHH-Beijing campaigns as a case study. (26th November 2020)

• Record Type: Journal Article
• Authors: Xu, Jingsha; Srivastava, Deepchandra; Wu, Xuefang; Hou, Siqi; Vu, Tuan V.; Liu, Di; Sun, Yele; Vlachou, Athanasia; Moschos, Vaios; Salazar, Gary; Szidat, Sönke; Prévôt, André S. H.; Fu, Pingqing; Harrison, Roy M.; Shi, Zongbo
• Is Part Of: Faraday discussions. Volume 226(2020)
• Page Start: 290
• Page End: 313
• Publication Date: 2020-11-26
• Subjects: Chemistry -- Periodicals; Metallurgy -- Periodicals; Electrochemistry -- Periodicals; 540
• DOI: 10.1039/d0fd00095g
• Languages: English
• ISSNs: 1359-6640

Abstract

Abstract : This paper reports an evaluation of multiple source apportionment methods for OC and PM2.5 . Abstract : This study aims to critically evaluate the source apportionment of fine particles by multiple receptor modelling approaches, including carbon mass balance modelling of filter-based radiocarbon ( 14 C) data, Chemical Mass Balance (CMB) and Positive Matrix Factorization (PMF) analysis on filter-based chemical speciation data, and PMF analysis on Aerosol Mass Spectrometer (AMS-PMF) or Aerosol Chemical Speciation Monitor (ACSM-PMF) data. These data were collected as part of the APHH-Beijing (Atmospheric Pollution and Human Health in a Chinese Megacity) field observation campaigns from 10 th November to 12 th December in winter 2016 and from 22 nd May to 24 th June in summer 2017. 14 C analysis revealed the predominant contribution of fossil fuel combustion to carbonaceous aerosols in winter compared with non-fossil fuel sources, which is supported by the results from other methods. An extended Gelencsér (EG) method incorporating 14 C data, as well as the CMB and AMS/ACSM-PMF methods, generated a consistent source apportionment for fossil fuel related primary organic carbon. Coal combustion, traffic and biomass burning POC were comparable for CMB and AMS/ACSM-PMF. There are uncertainties in the EG method when estimating biomass burning and cooking OC. The POC from cooking estimated by different methods was poorly correlated, suggesting a large uncertainty when differentiating this source type. The PM2.5 source apportionment results varied between different methods. Through a comparison and correlation analysis of CMB, PMF and AMS/ACSM-PMF, the CMB method appears to give the most complete and representative source apportionment of Beijing aerosols. Based upon the CMB results, fine aerosols in Beijing were mainly secondary inorganic ion formation, secondary organic aerosol formation, primary coal combustion and from biomass burning emissions.