Stereospecific synthesis of chiral P-containing polyaromatics based on 7-membered P-rings. Issue 59 (1st July 2021)

• Record Type: Journal Article
• Authors: Mokrai, Réka; Mocanu, Anabella; Duffy, Matthew P.; Vives, Thomas; Caytan, Elsa; Dorcet, Vincent; Roisnel, Thierry; Nyulászi, László; Benkő, Zoltán; Bouit, Pierre-Antoine; Hissler, Muriel
• Is Part Of: Chemical communications. Volume 57:Issue 59(2021)
• Page Start: 7256
• Page End: 7259
• Publication Date: 2021-07-01
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d1cc02293h
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Stereospecific synthesis and (chir)optical and redox properties of helicenoid-based phosphepine as well as chiral P-containing polycyclic aromatic hydrocarbons are presented. Abstract : We present the stereospecific synthesis of helicenoid-based phosphepines (7-membered P-rings) as well as chiral P-containing polycyclic aromatic hydrocarbons. In these systems, an axial to central chirality transfer takes place from the BINAP moiety to the P-atom. The impact of the molecular design on the structure, the (chir)optical (including circularly polarized luminescence) and redox properties are investigated.