Heterogeneous nanocomposites consisting of Pt3Co alloy particles and CoP2 nanorods towards high‐efficiency methanol electro‐oxidation. (19th May 2021) - Yang, Niuwa
Abstract: Heterogeneous nanocomposites comprising chemically distinct constituents are particularly promising in electrocatalysis. We herein report a synthetic strategy that combines the reduction of Pt and Co ionic precursors at an appropriate ratio with the subsequent phosphating at an elevated temperature for forming heterogeneous nanocomposites consisting of quasi‐spherical Pt3 Co alloy domains and rod‐like CoP2 domains for high‐efficiency methanol electro‐oxidation. The strong electronic coupling between Pt3 Co and CoP2 domains in the nanocomposites render the electron density around Pt atoms to decrease, which is favorable for reducing the adsorption of poisoning CO‐like intermediates on the catalyst surfaces. Accordingly, the as‐prepared heterogeneous Pt3 Co–CoP2 nanocomposites show good performance for methanol electro‐oxidation both in acidic and alkaline media. In specific, at a Pt loading of only 6.4% on a common carbon substrate, the mass‐based activity of Pt3 Co–CoP2 nanocomposites in an acidic medium is about 2 and 1.5 times as high as that of commercial Pt/C catalyst (20% mass loading) and home‐made Pt3 Co alloy nanoparticles (8.0% mass loading), while in the alkaline medium, these values are 3 and 2, respectively. Abstract : Heterogeneous Pt3 Co–CoP2 nanocomposites with favorable electronic configuration could weaken the absorption of poisoning CO‐like intermediates, which significantly boosts their catalytic activity and durability for the electrocatalytic oxidation of methanol.