Early stage of CVD graphene synthesis on Ge(001) substrate. (August 2018)

• Record Type: Journal Article
• Authors: Di Gaspare, L.; Scaparro, A.M.; Fanfoni, M.; Fazi, L.; Sgarlata, A.; Notargiacomo, A.; Miseikis, V.; Coletti, C.; De Seta, M.
• Is Part Of: Carbon. Volume 134(2018)
• Page Start: 183
• Page End: 188
• Publication Date: 2018-08
• Subjects: Carbon -- Periodicals; Carbone -- Périodiques; Koolstof; Toepassingen; Electronic journals; 546.681
• DOI: 10.1016/j.carbon.2018.03.092
• Languages: English
• ISSNs: 0008-6223

Abstract

Abstract: In this work we shed light on the early stage of the chemical vapor deposition of graphene on Ge(001) surfaces. By a combined use of μ-Raman and x-ray photoelectron spectroscopies, and scanning tunneling microscopy and spectroscopy, we were able to individuate a carbon precursor phase to graphene nucleation which coexists with small graphene domains. This precursor phase is made of C aggregates with different size, shape and local ordering which are not fully sp 2 hybridized. In some atomic size regions these aggregates show a linear arrangement of atoms as well as the first signature of the hexagonal structure of graphene. The carbon precursor phase evolves in graphene domains through an ordering process, associated to a re-arrangement of the Ge surface morphology. This surface structuring represents the embryo stage of the hills-and-valleys faceting featured by the Ge(001) surface for longer deposition times, when the graphene domains coalesce to form a single layer graphene film. Graphical abstract: Image 1