Visible light laser-induced graphene from phenolic resin: A new approach for directly writing graphene-based electrochemical devices on various substrates. (February 2018)

• Record Type: Journal Article
• Authors: Zhang, Zhuchan; Song, Mengmeng; Hao, Junxing; Wu, Kangbing; Li, Chunya; Hu, Chengguo
• Is Part Of: Carbon. Volume 127(2018)
• Page Start: 287
• Page End: 296
• Publication Date: 2018-02
• Subjects: Carbon -- Periodicals; Carbone -- Périodiques; Koolstof; Toepassingen; Electronic journals; 546.681
• DOI: 10.1016/j.carbon.2017.11.014
• Languages: English
• ISSNs: 0008-6223

Abstract

Abstract: The cost-effective construction of self-designed conductive graphene patterns on desired substrates is crucial to the fabrication of graphene-based electrochemical devices. Here, we report a new approach for the scalable construction of laser-induced graphene (LIG) patterns on diverse substrates by using phenolic resin (PR) as the precursor. The PR-based LIG, which was produced with smart and inexpensive 405 nm semiconductor lasers under ambient conditions, possesses several interesting properties, e.g., 3D porous structures, low resistance (∼44 Ω/sq), good mechanical property and a wide range of applicable substrates, e.g., polymer films, glass slides, metal foils, ceramic plates and plant leaves. The efficient absorption of laser light by PR coatings themselves or dopants such as metal salts and organic dyes is demonstrated critical to the formation of PR-based LIG by visible light lasers. Based on this technique, self-designed and highly conductive graphene arrays can be easily constructed on various substrates to fabricate all-carbon supercapacitors and electrochemical glucose biosensors. The unique properties of PR materials, including easy synthesis, tunable structure and composition, excellent film-formation ability and extremely low cost, thus foresee the promising applications of PR-based LIG in electrochemical fields. Graphical abstract: Image 1