Post-polymerization modification based on reactive fluorinated polymers reaction. Issue 8 (16th March 2021)

• Record Type: Journal Article
• Authors: Du, Yiying; Zeng, Qiugui; Yuan, Ling; He, Lirong
• Is Part Of: Journal of macromolecular science. Volume 58:Issue 8(2021)
• Page Start: 521
• Page End: 538
• Publication Date: 2021-03-16
• Subjects: Fluorinated polymers -- activated ester/amine exchange reaction -- trans-esterification -- para-fluoro-hydroxyl/amine/azide/thiol reaction -- post-polymerization modification; Polymers -- Periodicals; Polymerization -- Periodicals; 547.7
• DOI: 10.1080/10601325.2021.1903328
• Languages: English
• ISSNs: 1060-1325

Abstract

Abstract: Post-polymerization modification (PPM) techniques are extremely beneficial in terms of designing well-defined functional polymers for various applications. In particular, metal-free PMM based on fluorinated polymers has gained persistent attention of researchers. In this review, we summarized the development of reactive fluorinated polymers. It covers (i) activated esters/amine based on pentafluorophenol ester polymers; (ii) trans-esterification based on pentafluorophenol ester polymers; (iii) para-fluoro-hydroxyl/amine/azide/thiol reaction based on pentafluorophenyl containing polymers. Additionally, we present an outlook on possible PPM strategies that can be used to further construct complex functional polymers. Graphical Abstract: