Hydrothermal carbonisation of mechanically dewatered digested sewage sludge—Energy and nutrient recovery in centralised biogas plant. (1st August 2021)

• Record Type: Journal Article
• Authors: Hämäläinen, Anna; Kokko, Marika; Kinnunen, Viljami; Hilli, Tuomo; Rintala, Jukka
• Is Part Of: Water research. Volume 201(2021)
• Publication Date: 2021-08-01
• Subjects: Sewage sludge digestate -- Hydrothermal carbonisation -- Hydrochar -- Phosphorous -- Nutrient recovery -- Energy recovery; Water -- Pollution -- Research -- Periodicals; 363.7394
• DOI: 10.1016/j.watres.2021.117284
• Languages: English
• ISSNs: 0043-1354

Abstract

Highlights: Integration of HTC to biogas plant enhances biogas production and ammonium recovery. Hydrochar can serve as a combustible or as a phosphorous source in agriculture. Pharmaceuticals in sewage sludge digestate reduced below detection limit after HTC. Heavy metals concentrated in hydrochar but were below legislative limits. Abstract: This study aimed to assess the role of hydrothermal carbonisation (HTC) in digestate processing in centralised biogas plants receiving dewatered sludge from regional wastewater treatment plants and producing biomethane and fertilisers. Chemically conditioned and mechanically dewatered sludge was used as such (total solids (TS) 25%) or as diluted (15% TS) with reject water in 30 min or 120 min HTC treatments at 210 °C, 230 °C or 250 °C, and the produced slurry was filtered to produce hydrochars and filtrates. The different hydrochars contributed to 20–55% of the original mass, 72–88% of the TS, 74–87% of the energy content, 71–92% of the carbon, above 86% of phosphorous and 38–64% of the nitrogen present in the original digestates. The hydrochars' energy content (higher heating values were 11.3–12.2 MJ/kg-TS) were similar to that of the digestates, while the ash contents increased (from 43% up to 57%). HTC treatments produced filtrates in volumes of 42–76% of the dewatered digestate, having a soluble chemical oxygen demand (SCOD) of 28–44 g/L, of which volatile fatty acids (VFAs) contributed 10–34%, and methane potentials of 182–206 mL-CH4 /g-SCOD without any major indication of inhibition. All 32 pharmaceuticals detected in the digestates were below the detection limit in hydrochars and filtrates, save for ibuprofen and benzotriazole in filtrate, while heavy metals were concentrated in the hydrochars but below the national limits for fertiliser use, save for mercury. The integration of HTC to a centralised biogas plant was extrapolated to enhance the annual biogas production by 5% and ammonium recovery by 25%, and the hydrochar was estimated to produce 83 GJ upon combustion or to direct 350 t phosphorous to agriculture annually. Graphical abstract: Image, graphical abstract