Controlled Hetero‐Architectures of Au‐Nanoparticles‐Decorated ZnO Nanowires for Enhanced Field Electron Emission Displays. Issue 27 (20th July 2018)

• Record Type: Journal Article
• Authors: Chikate, Parameshwar R.; Daware, Krishna D.; Gavhane, Dnyaneshwar S.; Ma, Yuan‐Ron; Choudhary, Ram J.; Patil, Shankar I.; More, Mahendra A.; Phase, Deodatta M.; Gosavi, Suresh W.; Shirage, Parasharam M.; Devan, Rupesh S.
• Is Part Of: ChemistrySelect. Volume 3:Issue 27(2018)
• Page Start: 7891
• Page End: 7899
• Publication Date: 2018-07-20
• Subjects: Au@ZnO -- FE displays -- hetero-architectures -- spritzer-shaped nanowires -- XPS/UPS; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.201801282
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: The spitzer shaped pointed ZnO nanowires of diameter 120 nm and length ∼5‐6 μm synthesized via hydrothermal techniques were decorated with Au nanoparticles of diameter < 20 nm along their textural boundaries. The turn‐on field ( Eon ) of 1.56 V/μm required to draw current density of 10 μA/cm 2 from ZnO nanowires was reduced further to 0.96 V/μm after controlled decoration of Au nanoparticle, is significantly lower than pristine/doped ZnO nanostructures, Ag@ZnO, Au@ZnO, Au@CuO, and MoS2 @TiO2 heterostructure based field emission (FE) devices. The orthodoxy test confirmed the feasibility of field‐enhancement factor ( βFE ) of 4477 for Au/ZnO/ITO emitters. The enhanced FE behavior are attributed to pointed nanotips, individual dispersion of Au nanoparticles along the textural boundaries of ZnO nanowires, and enhanced energy well formation at their interface. Moreover, the density of state increases enormously due to the hetero‐structured interface of Au@ZnO and a significant amount of electrons from both Au and ZnO contribute for enhanced emission current density (2.1 mA/cm 2 @ 1.92 V/μm), and greatly stable electron emission. Our experiments suggest that the tunable hetero‐architectures of Au nanoparticles@ZnO nanowires hold the promises for applications in display screens and intense electron source. Abstract : The nano‐hetero‐architectures of Au nanoparticles decorated (left panel) spitzer shaped and tipped ZnO nanowires (right upper panel) resulted in lower work‐function of 4.3 eV (right lower panel). Au/ZnO/ITO emitters have significantly reduced Eon to 0.96 V/μm and showed highly stable electron emission, besides larger emission current density of 2.1 mA/cm 2 at a lower applied field of 1.92 V/μm.