A Dirhoda‐Heterocyclic Carbene. Issue 11 (29th January 2020)
- Record Type:
- Journal Article
- Title:
- A Dirhoda‐Heterocyclic Carbene. Issue 11 (29th January 2020)
- Main Title:
- A Dirhoda‐Heterocyclic Carbene
- Authors:
- Barnett, Harrison J.
Hill, Anthony F. - Abstract:
- Abstract: The linear μ‐carbido complex [Rh2 (μ‐C)Cl2 (dppm)2 ] (dppm=bis(diphenylphosphino)methane) reacts with dimethylacetylene dicarboxylate (DMAD) to afford [Rh2 (μ‐C)(μ‐DMAD)Cl2 (dppm)2 ], which features a bent RhCRh linkage (124.7°) that might be described as a dirhoda‐heterocyclic carbene, as demonstrated by coordination to further metal centers. Abstract : The first example of an isolable bent μ‐carbido complex, that behaves in a manner reminiscent of a heterocyclic carbene is described.
- Is Part Of:
- Angewandte Chemie international edition. Volume 59:Issue 11(2020)
- Journal:
- Angewandte Chemie international edition
- Issue:
- Volume 59:Issue 11(2020)
- Issue Display:
- Volume 59, Issue 11 (2020)
- Year:
- 2020
- Volume:
- 59
- Issue:
- 11
- Issue Sort Value:
- 2020-0059-0011-0000
- Page Start:
- 4274
- Page End:
- 4277
- Publication Date:
- 2020-01-29
- Subjects:
- carbide complexes -- carbodicarbenes -- dirhoda-heterocyclic carbenes -- metalla-aromaticity
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3773 ↗
http://www.interscience.wiley.com/jpages/1433-7851 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/anie.201912650 ↗
- Languages:
- English
- ISSNs:
- 1433-7851
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000500
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 17752.xml