DIRECT RADIOCARBON DATING OF CHARCOAL-BASED INK IN PAPYRI: A FEASIBILITY STUDY. Issue 6 (23rd December 2020)

• Record Type: Journal Article
• Authors: Fedi, Mariaelena; Barone, Serena; Carraresi, Luca; Dominici, Simona; Liccioli, Lucia
• Editors: Cherkinsky, Alex; Hadden, Carla S.
• Is Part Of: Radiocarbon. Volume 62:Issue 6(2020)
• Page Start: 1707
• Page End: 1714
• Publication Date: 2020-12-23
• Subjects: inks, -- papyri, -- radiocarbon AMS dating, -- small samples; Radiocarbon dating -- Periodicals; 930.1028505
• DOI: 10.1017/RDC.2020.94
• Languages: English
• ISSNs: 0033-8222

Abstract

ABSTRACT: When dating documents by radiocarbon ( 14 C), what we typically measure is the concentration of the support (e.g. paper, parchment, or papyrus). This can however lead to a possible misinterpretation of results because the support may be older than the writing itself. To minimize such a possible ambiguity, the ideal approach would be direct dating of the ink or color (if organic). Here we propose a feasibility study to date carbon-based black inks when deposited on papyrus, one of the most widespread writing supports used in the past. We prepared test samples, using a commercial papyrus and a homemade black ink, obtained combining modern charcoal fragments and Arabic gum. Even though the ink binder might have represented the best candidate to be dated, we verified by FTIR that the molecular composition of its soluble fraction is very similar to papyrus extractives, thus identifying the residual charcoals recovered after extraction as the most suitable material for the measurement. Enough charcoal material was extracted from the test samples and processed using our new setup optimized for microgram-size samples. The overall experimental procedure was found to be reproducible, and measured 14 C concentrations were coherent with the data obtained from larger samples and raw materials.