Fabrication of solid and hollow colloidosomes through self-assembly of micronsized polymer particles and their controlled transition. (16th July 2021)

• Record Type: Journal Article
• Authors: Jiang, Xubao; Cao, Hongyan; Zhang, Libin; Wu, Lili; Kong, Xiang Zheng
• Is Part Of: Polymer. Volume 228(2021)
• Publication Date: 2021-07-16
• Subjects: Uniform polymer particles -- Ethylene benzene droplet -- Adsorption energy -- Self-assembly -- Colloidosomes -- Morphology control; Polymers -- Periodicals; Polymerization -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; 547.7
• DOI: 10.1016/j.polymer.2021.123946
• Languages: English
• ISSNs: 0032-3861

Abstract

Abstract: Colloidal particles self-organize themselves, leading to their highly ordered arrays of superstructure, which are of high interests to understand the fundamental physics of complex colloids and of great potential in catalysts, filters, and optical or photovoltaic materials. Herein highly uniform polystyrene based polymer particles, P(St-TPTA), of 1 μm are first prepared through precipitation polymerization of styrene (St) and trihydroxymethyl propane triacrylate (TPTA) in ethanol. Colloidosomes were prepared by a simple self-assembly of these P(St-TPTA) primary particles in water-ethanol (H2 O–EtOH) binary solvent, with a third solvent (ethyl benzene, EB) as organic template. By varying the shaking frequency, assembly time, temperature, EB amount and TPTA amount in P(St-TPTA), spherical and solid colloidosomes of about 15 μm diameter were obtained at H2 O/EtOH volume ratio around 30/70. By increasing this ratio to about 80/20, hollow colloidosomes of about the same size were achieved. The formations of these colloidosomes and the transition from one to another form were well interpreted based on the adsorption energy of the primary particles on the interface of EB and H2 O–EtOH. This study provides an easy protocol, featured by absence of any additives in the entire process, for fabrication of hollow and solid colloidosomes with clear mechanism. Graphical abstract: Image 1 Highlights: Styrene (St) and trihydroxymethyl propane triacrylate (TPTA) are copolymerized. Highly uniform P(St-TPTA) primary particles are made by precipitation polymerization. Self-assembly of P(St-TPTA) particles is conducted in H2 O–EtOH binary solvent. Solid & hollow colloidosomes are formed with ethyl benzene droplets in H2 O–EtOH. Colloidosome formation mechanism and their transitions from one to another are stated.