MoO2–graphene nanocomposite as an electrocatalyst for high-performance vanadium redox flow battery. (August 2021)

• Record Type: Journal Article
• Authors: Bayeh, Anteneh Wodaje; Ou, Yang-Yi; Ou, Yun-Ting; Chang, Yu-Chung; Chen, Hsueh-Yu; Wang, Kai-Chin; Wang, Yao-Ming; Huang, Hsin-Chih; Chiang, Tai-Chin; Kabtamu, Daniel Manaye; Wang, Chen-Hao
• Is Part Of: Journal of energy storage. Volume 40(2021)
• Publication Date: 2021-08
• Subjects: Vanadium redox flow battery -- MoO2 -- reduced graphene oxide -- MoO2–rGO nanocomposite; Energy storage -- Periodicals; Energy storage -- Research -- Periodicals; 621.3126
• DOI: 10.1016/j.est.2021.102795
• Languages: English
• ISSNs: 2352-152X

Abstract

Highlights: MoO2 –rGO composite is synthesized through a hydrothermal approach. MoO2 nanoparticles on the rGO surface avoid restacking and aggregation. MoO2 –rGO composite improve mass transport at the electrode-electrolyte interface. Oxygen vacancies and oxygen functional groups play the role of active sites. MoO2 –rGO electrocatalyst acts as a robust electrode towards V3+/V2+ and VO2 + /VO 2+ . Abstract: MoO2 –reduced graphene oxide composite (MoO2 –rGO) acts as the electrode material for all-vanadium redox flow battery (VRFB). MoO2 –rGO composite exhibits excellent electrocatalytic redox reversibility for V 3+ /V 2+ and VO2 + /VO 2+ and larger anodic and cathodic peak currents than those of other individual MoO2 and rGO samples. The voltage efficiency of the VRFB using MoO2 –rGO nanocomposite at 80 mA cm −2 is 82.14%, which is 4.23% and 13.56% higher than the VRFBs using the rGO-coated graphite felt electrode and the graphite felt electrode, respectively. It still shows the voltage efficiencies of 73.83% and 68.50% at 120 mA cm −2 and 140 mA cm −2, respectively, but other samples have no effective discharge. This improvement is attributed to the uniform distribution of MoO2 nanoparticles on the rGO surface, avoiding the restacking of the rGO sheets and suppressing nanoparticle aggregation, which might increase the effective surface area and improve mass transport at the electrode-electrolyte interface. Furthermore, oxygen vacancies on MoO2, the high electrical conductivity of rGO, and the high content of oxygen functional groups act as active sites for the vanadium ion redox reaction.