Minimizing water consumption for sugar and lignin recovery via the integration of acid and alkali pretreated biomass and their mixed filtrate without post-washing. (October 2021)

• Record Type: Journal Article
• Authors: Zhao, Jikai; Yang, Yang; Zhang, Meng; Wang, Donghai
• Is Part Of: Bioresource technology. Volume 337(2021)
• Publication Date: 2021-10
• Subjects: Biomass valorization -- Acetic acid -- Sodium hydroxide -- Integration process -- Water saving; Biomass -- Periodicals; Biomass energy -- Periodicals; Bioremediation -- Periodicals; Agricultural wastes -- Periodicals; Factory and trade waste -- Periodicals; Organic wastes -- Periodicals; Bioénergie -- Périodiques; Déchets agricoles -- Périodiques; Déchets industriels -- Périodiques; Déchets organiques -- Périodiques; Déchets (Combustible) -- Périodiques; 662.88
• DOI: 10.1016/j.biortech.2021.125389
• Languages: English
• ISSNs: 0960-8524

Abstract

Graphical abstract: Highlights: Parallel pretreatment of biomass using HOAc and NaOH reagents were elucidated. Mixing HOAc and NaOH pretreated filtrate without washing reached a pH of 4.80. The recovered lignin had comparable characteristics with the commercial alkali lignin. Mixing HOAc and NaOH pretreated biomass and filtrate boosted sugar concentration. Abstract: Excessive post-washing of pretreated biomass leads to huge water consumption and chemical loss. To address this issue, parallel HOAc and NaOH pretreatments of biomass followed by integration of their biomass and filtrate were investigated. Pretreatment effectiveness including morphology, crystallinity, and component recovery, were elucidated. Results showed that HOAc and NaOH in the mixed filtrate were neutralized to achieve a pH of around 4.80 prompting the alkali lignin precipitation. Lignin (46.01 and 48.38 g/kg-biomass for hemp and poplar, respectively) exhibiting comparable FTIR characteristics with the commercial alkali lignin was recovered. Compared to sodium acetate buffer as a control, integrating HOAc and NaOH pretreated biomass and their mixed filtrate for enzymatic hydrolysis boosted total sugar concentration (hemp: 42.90 vs. 38.27 g/L; poplar: 43.18 vs. 38.76 g/L) without compromising glucose yield (hemp: 70.86 vs. 70.69%; poplar: 66.48 vs. 69.48%) but improving xylose yield (hemp: 60.10 vs. 35.92%; poplar: 56.90 vs. 29.39%).