Halogen bonding in polymer science: towards new smart materials. Issue 27 (5th July 2021)

• Record Type: Journal Article
• Authors: Kampes, Robin; Zechel, Stefan; Hager, Martin D.; Schubert, Ulrich S.
• Is Part Of: Chemical science. Volume 12:Issue 27(2021)
• Page Start: 9275
• Page End: 9286
• Publication Date: 2021-07-05
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/d1sc02608a
• Languages: English
• ISSNs: 2041-6520

Abstract

Abstract : The incorporation of halogen bonding into polymer architectures is a new approach for the design of functional materials. This perspective emphasizes the current development in the field of halogen bonding featuring polymer materials. Abstract : The halogen bond is a special non-covalent interaction, which can represent a powerful tool in supramolecular chemistry. Although the halogen bond offers several advantages compared to the related hydrogen bond, it is currently still underrepresented in polymer science. The structural related hydrogen bonding assumes a leading position in polymer materials containing supramolecular interactions, clearly indicating the high potential of using halogen bonding for the design of polymeric materials. The current developments regarding halogen bonding containing polymers include self-assembly, photo-responsive materials, self-healing materials and others. These aspects are highlighted in the present perspective. Furthermore, a perspective on the future of this rising young research field is provided.