Seasonal and spatial dynamics of selected pesticides and nutrients in a small lake catchment – Implications for agile monitoring strategies. (October 2021)

• Record Type: Journal Article
• Authors: Warner, Wiebke; Zeman-Kuhnert, Sebastian; Heim, Christine; Nachtigall, Solveig; Licha, Tobias
• Is Part Of: Chemosphere. Volume 281(2021)
• Publication Date: 2021-10
• Subjects: Agile monitoring strategies -- Pesticides -- Nutrients -- Small catchment dynamics -- WFD; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2021.130736
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: Intensive anthropogenic pressure such as high inputs of nutrients and pesticides severely threaten most European water bodies. Small catchments ≤10 km 2 are not monitored under the Water Framework Directive but play an important role in freshwater ecosystems. The high complexity in seasonal and spatial dynamics require more than a one-size-fits-all approach in water quality monitoring. Often located in rural areas with a high agricultural activity, small catchments often carry high amounts of nutrients, pesticides and their transformation products affecting drinking water resources. With a low-cost approach of a monthly sampling campaign over the course of one year combined with meaningful indicators for potential pollution sources within the catchment this study could elucidate catchment dynamics and two hotspots for pesticides and nutrients. Two different groups of pesticides were observed (I) pesticides on long-term use which were applied in high amounts over the last decades (e.g., chloridazon and its transformation products) and (II) pesticides on short-term use, newly introduced into the market. Especially transformation products of pesticides from group (I) together with nitrate showed a steady release from two fields into the receiving water bodies over the year, probably being stored in the soil layers over the years of application slowly leaching out. Pesticides from group (II) showed a strong seasonality, released from another hotspot area probably due to run-off shortly after application. Streamlining this knowledge into targeted measures and an agile monitoring strategy for the respective catchments may allow a sustainable improvement of water quality and a better ecosystem protection. Graphical abstract: Image 1 Highlights: Complex small lake systems need dynamic monitoring strategies. Patterns of nutrients and pesticides based on a one year sampling presented. Local hotspots within the catchment have a high impact on small catchments. Implications for information-rich sampling, agile water-quality monitoring.