Measurements of isochoric specific heat capacity for 3, 3, 3-trifluoroprop-1-ene (R1243zf) at temperatures from (250 to 300) K and pressures up to 10 MPa. (October 2021)

• Record Type: Journal Article
• Authors: Ding, Li; Sheng, Bowen; Hou, Yu; Dong, Xueqiang; Zhao, Yanxing; Xu, Hongbo; Shen, Jun; Gong, Maoqiong
• Is Part Of: Journal of chemical thermodynamics. Volume 161(2021)
• Publication Date: 2021-10
• Subjects: Adiabatic calorimeter -- R1243zf -- Isochoric specific heat capacity -- Compressed liquid; Thermodynamics -- Periodicals; Thermochemistry -- Periodicals; Thermodynamique -- Périodiques; Thermochimie -- Périodiques; Thermochemistry; Thermodynamics; Periodicals; 541.369
• DOI: 10.1016/j.jct.2021.106494
• Languages: English
• ISSNs: 0021-9614

Abstract

Highlights: Measurements were conducted by an adiabatic batch calorimeter with intermittent heating. The isochoric heat capacity for liquid R1243zf were measured. A comparation was made between the present data and the values calculated by three equations. Abstract: In this paper, a total of 86 isochoric specific heat capacity ( cv ) data of 3, 3, 3-trifluoroprop-1-ene (R1243zf) at temperatures from (250 to 300) K and pressures up to 10 MPa were measured using an adiabatic batch calorimeter. The standard uncertainties of temperature, pressure and isochoric specific heat capacity were estimated to be 12 mK, 5 kPa and 0.95%, respectively. A comparison was conducted between the experimental cv data and values calculated by three equations including the Helmholtz energy EOS (Akasaka and Lemmon, 2019) in REFPROP 10.0, the generalized equation (Zhong et al., 2019) and the corresponding states equation (Sheng et al., 2020) with the average absolute relative deviations (AARDs) of 2.43%, 0.91% and 0.84%, respectively. Among three equations, the corresponding states equation developed by Sheng et al. gives the best predictive performance for the liquid heat capacity of R1243zf.