A New 3D Coordination Polymer of Bismuth with Nicotinic Acid N-Oxide. (11th September 2013)

• Record Type: Journal Article
• Authors: Marandi, Farzin; Pantenburg, Ingo; Meyer, Gerd
• Other Names: Hamaker Christopher G. Academic Editor.
• Is Part Of: Journal of chemistry. Volume 2013(2013)
• Publication Date: 2013-09-11
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1155/2013/845810
• Languages: English
• ISSNs: 2090-9063

Abstract

Abstract : The new three-dimensional coordination polymer {[Bi(NNO)2 (NO3 )]·1.5H2 O} n (1, NNO − = nicotinate N -oxide) was synthesized and characterized by elemental analysis, IR and 1 H-NMR spectroscopy, as well as single-crystal X-ray diffraction analysis. 1 crystallizes in the monoclinic space group C2/c. The crystal structure consists of a rectangular-shaped grid constructed with NNO linkers. Cavities of a diameter of 7.9–8.3 Å 2 are filled with disordered water molecules. The thermal stability of the compound was evaluated by thermogravimetric analysis.